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Biomass burning plays an important role in climate-forcing and atmospheric chemistry. The drivers of fire activity over the past two centuries, however, are hotly debated and fueled by poor constraints on the magnitude and trends of preindustrial fire regimes. As a powerful tracer of biomass burning, reconstructions of paleoatmospheric carbon monoxide (CO) can provide valuable information on the evolution of fire activity across the preindustrial to industrial transition. Here too, however, significant disagreements between existing CO records currently allow for opposing fire histories. In this study, we reconstruct a continuous record of Antarctic ice core CO between 1821 and 1995 CE to overlap with direct atmospheric observations. Our record indicates that the Southern Hemisphere CO burden ([CO]) increased by 50% from a preindustrial mixing ratio of ca. 35 ppb to ca. 53 ppb by 1995 CE with more variability than allowed for by state-of-the-art chemistry-climate models, suggesting that historic CO dynamics have been not fully accounted for. Using a 6-troposphere box model, a 40 to 50% decrease in Southern Hemisphere biomass-burning emissions, coincident with unprecedented rates of early 20th century anthropogenic land-use change, is identified as a strong candidate for this mismatch. 

In paleoceanography, carbon and oxygen stable isotope ratios from benthic foraminifera are used as tracers of physical and biogeochemical properties of the deep ocean. We present the first version of the Ocean Carbon Cycling working group database,  of stable isotope ratios of oxygen and carbon from benthic foraminifera from deep ocean sediment cores from the Last Glacial Maximum (LGM, 23-20 ky before present (BP)) to the Holocene (<10 ky BP) with a particular focus on the early last deglaciation (20-15 ky BP). It includes 287 globally distributed coring sites, with metadata, isotopic and chronostratigraphic information, and age models. A quality check was performed for all data and age models. Sites with at least millennial resolution were preferred, because the main goal is to resolve ocean changes associated with the last deglaciation on at least millennial timescales. Software tools were produced to access and analyze the data, and are included with this publication. Deep water mass structure as well as differences between the early deglaciation and LGM are captured by the data in the compilation, even though its coverage is still sparse in many ocean regions. We find high correlations among time series calculated with different age models at sites that allow such analysis. The database provides a useful dynamical approach to map physical and biogeochemical changes of the ocean throughout the last deglaciation.</p> Custom python scripts to read and analyze the data base may be found in https://github.com/juanmuglia/OC3-python-scripts and in OC3-python-scripts.zip in this repository. plots_d13c.pdf and plots_d18o.pdf contain time series for all sites and available age models. 

Abstract We present the first version of the Ocean Circulation and Carbon Cycling (OC3) working group database, of oxygen and carbon stable isotope ratios from benthic foraminifera in deep ocean sediment cores from the Last Glacial Maximum (LGM, 23-19 ky) to the Holocene (<10 ky) with a particular focus on the early last deglaciation (19-15 ky BP). It includes 287 globally distributed coring sites, with metadata, isotopic and chronostratigraphic information, and age models. A quality check was performed for all data and age models, and sites with at least millennial resolution were preferred. Deep water mass structure as well as differences between the early deglaciation and LGM are captured by the data, even though its coverage is still sparse in many regions. We find high correlations among time series calculated with different age models at sites that allow such analysis. The database provides a useful dynamical approach to map physical and biogeochemical changes of the ocean throughout the last deglaciation. 

Abstract. Amino acid racemization (AAR) geochronology is a powerful tool for datingQuaternary marine sediments across the globe, yet its application to ArcticOcean sediments has been limited. Anomalous rates of AAR in foraminiferafrom the central Arctic were reported in previously published studies,indicating that either the rate of racemization is higher in this area, orinaccurate age models were used to constrain the sediment ages. This studyinvestigates racemization rates in foraminifera from three well-datedsediment cores taken from the Yermak Plateau during the 2015 TRANSSIZ (TRansitions in the Arctic Seasonal Sea Ice Zone) expedition on RV Polarstern. D and L isomers of the amino acids asparticacid (Asp) and glutamic acid (Glu) were separated in samples of theplanktic foraminifer Neogloboquadrina pachyderma and the benthic species Cassidulina neoteretis to quantify the extent ofracemization. In total, 241 subsamples were analysed, extending back tomarine oxygen isotope stage (MIS) 7. Two previously published powerfunctions, which relate the extent of racemization of Asp and Glu inforaminifera to sample age are revisited, and a comparison is made betweenthe ages predicted by these calibrated age equations and independentgeochronological constraints available for the cores. Our analyses reveal anexcellent match between ages predicted by a global compilation ofracemization rates for N. pachyderma and confirm that a proposed Arctic-specificcalibration curve is not applicable at the Yermak Plateau. These resultsgenerally support the rates of AAR determined for other cold bottom watersites and further highlight the anomalous nature of the purportedly highrate of racemization indicated by previous analyses of central Arcticsediments.